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Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes

Molecules (2016) 21(10)
DOI: 10.3390/molecules21101376
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Abstract

The reactions of isolable dialkylsilylene 1 with aromatic acyl chlorides afforded aroylsilanes 3a-3c exclusively. Aroylsilanes 3a-3c were characterized by 1H-, 13C-, and 29Si-NMR spectroscopy, high-resolution mass spectrometry (HRMS), and single-crystal molecular structure analysis. The reaction mechanisms are discussed in comparison with related reaction of 1 with chloroalkanes and chlorosilanes.

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Xiao, X. Q., Liu, X., Lu, Q., Li, Z., Lai, G., & Kira, M. (2016). Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes. Molecules, 21(10). https://doi.org/10.3390/molecules21101376

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