Synthesis of 4-tert-octylphenol and 4-cumylphenol by metal triflate and metal triflimidate catalysts

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Abstract

Metal inflates and metal triflimidates are shown to catalyse efficiently the Friedel-Crafts alkylation of phenol with alkenes. Bismuth, copper and scandium triflates lead to very good yields with excellent para-selectivities.

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Le Rouzo, G., Morel-Grepet, M., & Simonato, J. P. (2006). Synthesis of 4-tert-octylphenol and 4-cumylphenol by metal triflate and metal triflimidate catalysts. Journal of Chemical Research, (8), 521–522. https://doi.org/10.3184/030823406778256342

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