Potential air emission impacts of cellulosic ethanol production at seven demonstration refineries in the United States

Abstract

This paper reports on the estimated potential air emissions, as found in air permits and supporting documentation, for seven of the first group of precommercial or "demonstration" cellulosic ethanol refineries (7CEDF) currently operating or planning to operate in the United States in the near future. These seven refineries are designed to produce from 330,000 to 100 million gal of ethanol per year. The overall average estimated air emission rates for criteria, hazardous, and greenhouse gas pollutants at the 7CEDF are shown here in terms of tons per year and pounds per gallon of ethanol produced. Water use rates estimated for the cellulosic ethanol refineries are also noted. The air emissions are then compared with similar estimates from a U.S. cellulosic ethanol pilot plant, a commercial Canadian cellulosic ethanol refinery, four commercial U.S. corn ethanol refineries, and U.S. petroleum refineries producing gasoline. The U.S. Environmental Protection Agency (EPA) air pollution rules that may apply to cellulosic ethanol refineries are also discussed. Using the lowest estimated emission rates from these cellulosic ethanol demonstration facilities to project air emissions, EPA's major source thresholds for criteria and hazardous air pollutants might not be exceeded by cellulosic ethanol refineries that produce as high as 25 million gal per year of ethanol (95 ML). Emissions are expected to decrease at cellulosic ethanol refineries as the process matures and becomes more commercially viable. Copyright 2010 Air & Waste Management Association.