A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine)

  • Shepherd H
  • Tonge G
  • Hatcher L
  • et al.
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Abstract

A high pressure single crystal X-ray diffraction and Raman spectroscopy study has revealed a similar mechanism for both thermal and pressure-induced spin crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine) and the concomitant anion order-disorder transition.

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Shepherd, H., Tonge, G., Hatcher, L., Bryant, M., Knichal, J., Raithby, P., … Teat, S. (2016). A High Pressure Investigation of the Order-Disorder Phase Transition and Accompanying Spin Crossover in [FeL12](ClO4)2 (L1 = 2,6-bis{3-methylpyrazol-1-yl}-pyrazine). Magnetochemistry, 2(1), 9. https://doi.org/10.3390/magnetochemistry2010009

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