Communications: Can one identify nonequilibrium in a three-state system by analyzing two-state trajectories?

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Abstract

For a three-state Markov system in a stationary state, we discuss whether, on the basis of data obtained from effective two-state (or on-off) trajectories, it is possible to discriminate between an equilibrium state and a nonequilibrium steady state. By calculating the full phase diagram we identify a large region where such data will be consistent only with nonequilibrium conditions. This regime is considerably larger than the region with oscillatory relaxation, which has previously been identified as a sufficient criterion for nonequilibrium. © 2010 American Institute of Physics.

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Amann, C. P., Schmiedl, T., & Seifert, U. (2010). Communications: Can one identify nonequilibrium in a three-state system by analyzing two-state trajectories? Journal of Chemical Physics, 132(4). https://doi.org/10.1063/1.3294567

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