The rapid synthesis of an amide hydrogen bond templated [1]rotaxane is reported-demonstrating a potential pathway to synthetic analogues of lasso peptides. The structures of the [1]rotaxane and its unthreaded isomer have been characterized by NMR spectroscopy and modelled using DFT calculations. This journal is
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Young, M. J., Akien, G. R., & Evans, N. H. (2020). An amide hydrogen bond templated [1]rotaxane displaying a peptide motif-demonstrating an expedient route to synthetic mimics of lasso peptides. Organic and Biomolecular Chemistry, 18(27), 5203–5209. https://doi.org/10.1039/d0ob01190h