Liquid phase hydrogenation of MIBK over M/CsPW (M = Ag, Ru, Pt, and Pd)

Abstract

Four different metal nanoparticles (metal = Ag, Ru, Pt, or Rh) were impregnated on the acidic cesium salt of tungstophosphoric acid Cs2.5 H0.5 PW12 O40 (CsPW) with a loading amount of 2 wt%. The prepared catalysts were characterized by using X-ray diffraction (XRD), Fourier transform-infrared spectroscopy (FTIR), N2 sorption measurements, scanning electron microscopy (SEM), and energy-dispersive X-ray spectroscopy (EDX). Results confirmed the formation of highly distributed metallic nanoparticle centres over the acidic CsPW. The catalytic activity of the prepared catalysts were evaluated in the liquid phase hydrogenation of methyl isobutyl ketone (MIBK) to 2-methylpentane (2-MP) at 453 K. Pd-CsPW showed the highest activity compared to other catalysts, where 10% conversion was obtained with 91% selectivity after 4 h’s reaction time.