Sediment Heavy Metal Pollution Assessment in Changwang and Wuyuan Rivers in Hainan Island, China

Abstract

Heavy metal pollution may pose a significant threat to aquatic ecosystems. To assess heavy metal pollution, sediment samples were collected from Changwang and Wuyuan Rivers between June and December 2019. An inductively coupled plasma mass spectrometer was used to analyze the concentrations of As, Cd, Co, Cr, Cu, Mn, Ni, Pb, and Zn. The results revealed that Changwang River had significantly high concentrations of Cr (240.70 mg kg−1), Co (36.02 mg kg−1), Ni (108.70 mg kg−1), and Cu (36.61 mg kg−1), whereas As (7.55 mg kg−1) was elevated in Wuyuan River. In addition, Cd, As, Pb and Zn concentrations were below China’s sediment quality standard limits (GB 3838-2002), but the Cr level exceeded the limit. However, Cr and Ni exceeded the probable effect concentrations (PEC) and thus may cause toxic effects. The contamination factor, geo-accumulation index, and modified degree of contamination revealed that Changwang experienced considerable to very high heavy metal pollution, while Wuyuan had low to moderate pollution. The pollution load index demonstrated that the rivers were polluted during all seasons. Additionally, the risk index showed considerable and moderate risks in Changwang and Wuyuan, respectively. The metal ecological risk was ranked as Cd > Ni > As > Co > Cu > Cr > Mn > Pb > Zn. Multivariate analyses categorized heavy metals into two groups based on their potential sources: group one included Cr, Co, Ni, Cu, Mn, and Zn, while group two contained As, Cd, and Pb. The study provides valuable data on heavy metal pollution, which needs improvement for the studied rivers. The data can be used to assess pollution risks and manage riverine sediment quality.