Dual immobilization of magnetite nanoparticles and biosilica within alginate matrix for the adsorption of Cd(II) from aquatic phase

Abstract

The adsorption of cadmium ions by magnetite (Fe3O4)@biosilica/alginate (MBA nano-hybrid) was the main aim of the present investigation. Herein, MBA nano-hybrid was synthesized via chemical precipitation technique. As-synthesized MBA nano-hybrid was characterized using FT-IR, FESEM and XRD analyzes. Based on the results, the maximum adsorption capacity of the adsorbent for the removal of Cd(II) was obtained at the initial pH of 7.0. At the initial Cd(II) concentration of 40 mg/L, increasing the reaction time to 180 min led to the Cd adsorption of 35.36 mg/g. Since the removal of Cd(II) after the reaction time of 60 min was insignificant, the reaction time of 60 min was considered as optimum reaction time for performing the experimental runs. According to the results, Langmuir isotherm and pseudo-second order kinetic models were the best fitted models with high correlation coefficients (R2 > 0.99). The results of thermodynamic study indicated exothermic (positive ΔH°) and spontaneous nature (negative ΔG°) of the adsorption of Cd(II) on the surface of MBA nano-hybrid. Negligible reduction in the adsorption capacity of the nano-hybrid was observed (16.57%) after fifth experimental runs, indicating high reusability potential of the as-synthesized nano-hybrid adsorbent.