Construction of Porous Carbon Nanosheet/Cu2S Composites with Enhanced Potassium Storage

Abstract

Porous C nanosheet/Cu2S composites were prepared using a simple self-template method and vulcanization process. The Cu2S nanoparticles with an average diameter of 140 nm are uniformly distributed on porous carbon nanosheets. When used as the anode of a potassium-ion battery, porous C nanosheet/Cu2S composites exhibit good rate performance and cycle performance (363 mAh g−1 at 0.1 A g−1 after 100 cycles; 120 mAh g−1 at 5 A g−1 after 1000 cycles). The excellent electrochemical performance of porous C nanosheet/Cu2S composites can be ascribed to their unique structure, which can restrain the volume change of Cu2S during the charge/discharge processes, increase the contact area between the electrode and the electrolyte, and improve the electron/ionic conductivity of the electrode material.