Simple mononuclear cobalt(II) complex: A single-molecule magnet showing two slow relaxation processes

125Citations
Citations of this article
64Readers
Mendeley users who have this article in their library.

You may have access to this PDF.

Abstract

Complex [Co(PPh3)2Br2] possesses intermediate magnetic anisotropy, D/hc = -13 cm-1. It displays superparamagnetic behavior either in the absence of the magnetic field or in fields of Bdc = 0.05, 0.1, 0.15, and 0.2 T. At Bdc = 0.1 T, the barrier to spin reversal U/kB = 37 K and the extrapolated relaxation time τ0 = 9.4 × 10-11 s confirm its classification as a single-molecule magnet. At Bdc = 0.2 T, two relaxation processes are evidenced. © 2014 American Chemical Society.

Cite

CITATION STYLE

APA

Boča, R., Miklovič, J., & Titiš, J. (2014). Simple mononuclear cobalt(II) complex: A single-molecule magnet showing two slow relaxation processes. Inorganic Chemistry, 53(5), 2367–2369. https://doi.org/10.1021/ic5000638

Register to see more suggestions

Mendeley helps you to discover research relevant for your work.

Already have an account?

Save time finding and organizing research with Mendeley

Sign up for free