Study of boron–nitrogen dative bonds using azetidine inversion dynamics

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Abstract

A method for probing the strength of B–N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by 11B NMR, X-ray crystallography and MP2 calculations. © 2013 The Royal Society of Chemistry.

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Hoang, C. T., Prokes, I., Clarkson, G. J., Rowland, M. J., Tucker, J. H. R., Shipman, M., & Walsh, T. R. (2013). Study of boron–nitrogen dative bonds using azetidine inversion dynamics. Chemical Communications, 49(25), 2509–2511. https://doi.org/10.1039/c3cc36159d

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