Abstract
Twice the fun: Dimeric FeII diphosphonium bis(alkynyl) complexes are formed by oxidation of the corresponding FeII alkynyl phosphine complexes. The structure of these organometallic diphosphonium salts and their monomeric precursors were established by X-ray crystallography. The P-P bond can be cleaved by two-electron reduction to regenerate the monomers. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Tohmé, A., Grelaud, G., Argouarch, G., Roisnel, T., Labouille, S., Carmichael, D., & Paul, F. (2013). Redox-induced reversible P-P bond formation to generate an organometallic σ4λ4-1,2-biphosphane dication. Angewandte Chemie - International Edition, 52(16), 4445–4448. https://doi.org/10.1002/anie.201208682
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