Organocatalytic Enantioselective Strecker Reaction with Seven-Membered Cyclic Imines

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Abstract

A highly enantioselective Strecker reaction with dibenzo[b,f][1,4]oxazepines has been described using a dihydroquinine-derived thiourea as organocatalyst. The reaction affords chiral 10,11-dihydrodibenzo[b,f][1,4]oxazepine 11-carbonitrile derivatives in excellent yields (up to 99%) and excellent enantioselectivities (up to 98%) under mild reaction conditions. (Figure presented.).

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Lluna-Galán, C., Blay, G., Fernández, I., Muñoz, M. C., Pedro, J. R., & Vila, C. (2018). Organocatalytic Enantioselective Strecker Reaction with Seven-Membered Cyclic Imines. Advanced Synthesis and Catalysis, 360(19), 3662–3666. https://doi.org/10.1002/adsc.201800754

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