Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window

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Abstract

Synthesis, electronic and structural properties of a chiral NHC bearing a N-bonded cationic [4]helicene moiety are reported. This ligand is used to construct AuI, AuIIIand RhIcomplexes exhibiting far-red (chir)optical properties regardless of the metal.

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Tarrieu, R., Delgado, I. H., Zinna, F., Dorcet, V., Colombel-Rouen, S., Crévisy, C., … Lacour, J. (2021). Hybrids of cationic [4]helicene and N-heterocyclic carbene as ligands for complexes exhibiting (chir)optical properties in the far red spectral window. Chemical Communications, 57(31), 3793–3796. https://doi.org/10.1039/d1cc00898f

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