Catalytic asymmetric S-H insertion reaction of carbenoids

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Abstract

Catalytic asymmetric S-H insertion of carbenoids generated from aryldiazoacetates has been investigated with a number of chiral Rh(II) and Cu(I) catalysts. 12%-23% ee enantioselectivity were achieved with chiral Rh(II) catalysts.

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Zhang, X., Ma, M., & Wang, J. (2003). Catalytic asymmetric S-H insertion reaction of carbenoids. Arkivoc, 2003(2), 84–91. https://doi.org/10.3998/ark.5550190.0004.210

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