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Ferrocenyl thiolates as ligands in the enantioselective copper-catalyzed substitution of allylic acetates with Grignard reagents

Synlett (2001) (SPEC. ISS) 923-926
DOI: 10.1055/s-2001-14667
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Abstract

The application of ferrocenyl thiolates as ligands in copper-catalyzed asymmetric substitution reactions of allylic acetates with Grignard reagents is reported. The catalyst formed from lithium thiolate 12 gave the γ-products in high selectivity and with up to 64% ee.

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Karlström, A. S. E., Huerta, F. F., Meuzelaar, G. J., & Bäckvall, J. E. (2001). Ferrocenyl thiolates as ligands in the enantioselective copper-catalyzed substitution of allylic acetates with Grignard reagents. Synlett, (SPEC. ISS), 923–926. https://doi.org/10.1055/s-2001-14667

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