Seasonal Water Column Stratification and Manganese and Iron Distribution in a Water Reservoir: The Case of Pinios Dam (Western Greece)

Abstract

Climate change and extreme events such as droughts, heavy rainfall and flooding can influence the water column stratification in reservoir dams, decrease storage capacity, increase sediment and pollutant loads and, as a result, affect water quality. The seasonal variation in the water column stratification of reservoirs is an important parameter for the study of dam life cycle as well as water management and use. In the present study a detailed bathymetric survey was carried out, and a digital elevation model (DEM) of the reservoir was constructed. Seasonal physicochemical monitoring data such as temperature, dissolved oxygen, pH and conductivity are presented. The seasonal thermal stratification was recorded, resulting in an isolated hypolimnion where anoxic layers formed below 17 m in summer and autumn. Manganese and iron concentrations exhibited values higher than 150 mg/L in the anoxic hypolimnion during summer and autumn, indicating solubilization from the sediment. The observed seasonal and depth-dependent variations in physicochemical parameters underline the reservoir’s susceptibility to eutrophication and metal mobilization, particularly during stratified periods. These findings are critical for designing management strategies to mitigate potential water quality issues.