Abstract
(Figure Presented) Fluoride clusters of lanthanoids can be prepared in organic solvents by metathetical reactions of Ln(SePh)3 with NH 4F. The first products of these reactions, [(py)24Ln 28F68(SePh)16] (Ln = Pr, Nd; py = pyridine; see structure), are currently the largest discrete lanthanoid clusters ever isolated. Emission experiments on the neodymium compound reveal a near-IR quantum efficiency of 41%. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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Romanelli, M., Kumar, G. A., Emge, T. J., Riman, R. E., & Brennan, J. G. (2008). Intense near-IR emission from nanoscale lanthanoid fluoride clusters. Angewandte Chemie - International Edition, 47(32), 6049–6051. https://doi.org/10.1002/anie.200801530
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