Oil spills in a tropical Country - Brazilian case studies

Abstract

Faced with the latest experiences on Brazilian oil spill incidents, Petrobras has been trying to overcome many challenges in environmental management and operational safety, aiming to prevent environmental risks. This paper presents the oil characterizations and monitoring studies in affected ecosystems such as the hot spots on soils affected by the Iguassu River oil spill (occurred in July 2000, due to a pipeline rupture in the scraper area of REPAR, a Petrobras refinery located in the state of Parana), by the Vessel Vergina II oil spill in São Sebastião channel (located in the state of São Paulo, occurred in November 2000) and lastly, the Guanabara Bay oil spill (a pipeline rupture that occurred in January 2000, due to a pipeline rupture between oil terminal and REDUC, a Petrobras refinery located in the state of Rio de Janeiro). Chemical analysis were performed in different sample matrixes including many parameters such as total petroleum hydrocarbons (TPH), aliphatic compounds (n-alkanes), unresolved complex mixtures (UCM), benzene, toluene, ethylbenzene and xylenes (BTEX), polycyclic aromatic hydrocarbons (PAH), terpanes and steranes, that are the parameters usually monitored after a spill oil. Visual inspections were also performed mainly in Guanabara Bay in order to identify the affected ecosystems by the spilled oil and to plot maps of classified regions based on the level of visual oil contamination. The acute toxicity was evaluated in water soluble fraction (WSF) of the spilled oils using ecotoxicological tests.