Reactions of a β-diketiminate zinc hydride complex with heterocumulenes

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Abstract

The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO 2, C(Ni-Pr)2 and t-BuNCO at ambient temperature with insertion into the Zn-H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes. © 2010 The Royal Society of Chemistry.

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Schulz, S., Eisenmann, T., Schmidt, S., Bläser, D., Westphal, U., & Boese, R. (2010). Reactions of a β-diketiminate zinc hydride complex with heterocumulenes. Chemical Communications, 46(38), 7226–7228. https://doi.org/10.1039/c0cc01329c

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