βcyclodextrin-bonded silica particles as novel sorbent for stir bar sorptive extraction of phenolic compounds

Abstract

A stir bar coated with βcyclodextrin-bonded-silica (CDS) as novel sorbent has been developed and used to analyze seven phenolic compounds in aqueous samples, followed by thermal desorption and gas chromatography-mass spectrometric detection. Significant parameters affecting sorption process such as the time and temperature of sorption and desorption, ionic strength, pH and stirring rate have been optimized and discussed. The coating has a high thermal stability up to 300°C and long application lifetime (80 times). The porous structure of CDS coating provides high surface area and allows high extraction efficiency. Under the selected conditions, linearity range of 0.1-400 μg/L, limit of quantifications of 0.08-3.3 μg/L and method detection limits of 0.02-1.00 μg/L have been obtained. A satisfactory repeatability (RSD ≤ 6.5%, n = 7) with good linearity (0.9975 ≤ r2 ≤ 0.9996) of results illustrated a good performance of the present method. The recovery of different natural water samples was higher than 81.5%.