Electron collisions with molecular hydrogen from electronically excited states using the R-matrix method

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Abstract

Cross section data for electron impact electronic excitation of electronically excited states of H2 are computed using fixed-nuclear R-matrix calculations. Specifically, there is a focus on transitions from the quasi-metastable excited states a3Sg+ and c 3?u. Data are compared with known theoretical data where available. Our calculations suggest that the published cross sections are generally too large in the low energy (<20 eV) collision region. The effect of shifting the electronic excitation thresholds to those given by essentially exact calculations is tested.

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Meltzer, T., & Tennyson, J. (2020). Electron collisions with molecular hydrogen from electronically excited states using the R-matrix method. Journal of Physics B: Atomic, Molecular and Optical Physics, 53(24). https://doi.org/10.1088/1361-6455/abc3d1

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