Coordination-directed self-assembly of a simple benzothiadiazole-fused tetrathiafulvalene to low-bandgap metallogels

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Abstract

Coordination-driven gelation of a benzothiadiazole-fused tetrathiafulvalene (TTF) is demonstrated. This is the first work reporting highly stable metallogels based on a donor-acceptor conjugate with such a simple structure for the construction of new low-bandgap materials with various functional properties and novel nanostructures.

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Amacher, A. M., Puigmartí-Luis, J., Geng, Y., Lebedev, V., Laukhin, V., Krämer, K., … Liu, S. X. (2015). Coordination-directed self-assembly of a simple benzothiadiazole-fused tetrathiafulvalene to low-bandgap metallogels. Chemical Communications, 51(81), 15063–15066. https://doi.org/10.1039/c5cc06819c

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