Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex

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Abstract

A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl2 complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography. © The Partner Organisations 2014.

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Gavette, J. V., Klug, C. M., Zakharov, L. N., Shores, M. P., Haley, M. M., & Johnson, D. W. (2014). Intramolecular N–H⋯Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl2 complex. Chemical Communications, 50(54), 7173–7175. https://doi.org/10.1039/c4cc02297a

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