Abstract
A novel chlorinating reagent with a high concentration of HCl has enabled the highly regioselective hydrochlorination of unactivated alkynes using a commercial nanogold catalyst. No overchlorination or hydration products were formed, and various functional groups were tolerated. This hydrochlorination method could be conducted under open air.
Cite
CITATION STYLE
APA
Liang, S., Ebule, R., Hammond, G. B., & Xu, B. (2017). A Chlorinating Reagent Yields Vinyl Chlorides with High Regioselectivity under Heterogeneous Gold Catalysis. Organic Letters, 19(17), 4524–4527. https://doi.org/10.1021/acs.orglett.7b02101
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