Fe3 o4 @c nanoparticles synthesized by in situ solid-phase method for removal of methylene blue

Abstract

Fe3 O4 @C nanoparticles were prepared by an in situ, solid-phase reaction, without any precursor, using FeSO4, FeS2, and PVP K30 as raw materials. The nanoparticles were utilized to decolorize high concentrations methylene blue (MB). The results indicated that the maximum adsorption capacity of the Fe3O4@C nanoparticles was 18.52 mg/g, and that the adsorption process was exothermic. Additionally, by employing H2 O2 as the initiator of a Fenton-like reaction, the removal efficiency of 100 mg/L MB reached ~99% with Fe3 O4 @C nanoparticles, while that of MB was only ~34% using pure Fe3 O4 nanoparticles. The mechanism of H2 O2 activated on the Fe3 O4 @C nanoparticles and the possible degradation pathways of MB are discussed. The Fe3 O4 @C nanoparticles retained high catalytic activity after five usage cycles. This work describes a facile method for producing Fe3 O4 @C nanoparticles with excellent catalytic reactivity, and therefore, represents a promising approach for the industrial production of Fe3 O4 @C nanoparticles for the treatment of high concentrations of dyes in wastewater.