Abstract
Neptunium behaviour in an LiCl-KCl eutectic melt at 723 K was studied using spectroelectro-chemistry. Cathodic reduction of neptunium(IV)-containing melts led to the formation of Np(III) ions and then neptunium metal. Electronic absorption spectra of Np(IV) and Np(III) chloro species in LiCl-KCl melt were recorded and resolved into individual Gaussian bands. The nature of neptunium complex ions in the melt is discussed. © 2007 Verlag der Zeitschrift für Naturforschung.
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Polovov, I. B., Sharrad, C. A., May, I., Volkovich, V. A., & Vasin, B. D. (2007). Spectroelectrochemical study of neptunium in molten LiCl-KCl eutectic. In Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences (Vol. 62, pp. 745–748). Verlag der Zeitschrift fur Naturforschung. https://doi.org/10.1515/zna-2007-1212
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