Abstract
Oxyfunctionalisation reactions in neat substrate still pose a challenge for biocatalysis. Here, we report an alginate-confined peroxygenase-CLEA to catalyse the enantioselective epoxidation of cis-β-methylstyrene in a solvent-free reaction system achieving turnover numbers of 96 000 for the biocatalyst and epoxide concentrations of 48 mM.
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CITATION STYLE
APA
Nintzel, F. E. H., Wu, Y., Planchestainer, M., Held, M., Alcalde, M., & Hollmann, F. (2021). An alginate-confined peroxygenase-CLEA for styrene epoxidation. Chemical Communications, 57(47), 5766–5769. https://doi.org/10.1039/d1cc01868j
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