The use of supramolecular interactions to control and direct excited-state reactivity is described, with emphasis on the author's contributions in this area. The systems are based on the multiple-point hydrogen-bonding molecular recognition motif present in the melamine-barbituric acid system, and are designed to operate in solution phase. Despite the weak nature of non-covalent interactions, control of high energy intermediates such as excited cinnamantes, stilbenes, or fullerenes is possible. These results demonstrate the particular sensitivity of short-lived electronically excited molecules to their environment, and particularly to the mutual orientation of the reactants. © Schweizerische Chemische Gesellschaft.
CITATION STYLE
Bassani, D. M. (2006). From supramolecular photochemistry to self-assembled photoactive architectures: The emergence of photochemical nanosciences. In Chimia (Vol. 60, pp. 175–178). Swiss Chemical Society. https://doi.org/10.2533/000942906777674796
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