NOM (HA and FA) reduction in water using nano titanium dioxide photocatalysts (P25 and P90) and membranes

Abstract

This study examined the removal of natural organic substances (humic acids-HA, and fulvic acids-FA) from model solutions using photocatalysis and ultrafiltration. The effect of two nano titanium dioxide types (P25 and P90) with different active surface areas and two UV lamps (low-pressure and medium-pressure) on the effectiveness of FA and HA removal during photocatalysis was tested. An integrated photocatalytic + ultrafiltration system was also analyzed to determine the effectiveness of FA and HA removal and the changes in the relative permeate flux (Ultrafiltration Membrane Fouling-UF). We observed that photocatalysis using the P90 nano titanium dioxide was more efficient than the P25 due to the larger surface area (2×). The decomposition of organic substances proceeded efficiently up to 30 min of solution exposure, and the use of a medium-pressure lamp accelerated compound decomposition relative to the low-pressure lamp. The applied photocatalysis + ultrafiltration system was characterized by a high degree of FA removal while improved hydraulic efficiency was observed during ultrafiltration.