Synthesis, local structure and optical property studies of a-SnS microrods by synchrotron X-ray pair distribution function and micro-Raman shift

Abstract

A hydrothermal synthesis method was employed for the preparation of tin sulfide (a-SnS) microrod samples (SnS-A and SnS-B) using ethylenediamine and deionized water as the surfactant at ratios from 50?:?50 to 100?:?00. The atomic structures of the a-SnS microrods were studied using atomic pair distribution function (PDF) analysis and total synchrotron X-ray scattering data. The synchrotron X-ray diffraction (ScXRD) patterns and PDF data reveal that the structure of the SnS microrods is orthorhombic. From the refinement of the PDF, the first and second peaks correspond to nearest (Sn2+-S2-) and second nearest distances (Sn2+-Sn2+) of 2.546 (0.003) Å and 4.106 (0.004) Å, and 2.527 (0.005) Å and 4.087 (0.006) Å for SnS-A and SnS-B samples, respectively. The TEM results show that samples SnS-A and SnS-B have a microrod structure, with microrod diameters of 800 nm and 500 nm with lengths of tens of micrometers, respectively. The SnS-A and SnS-B samples show a direct band gap of 1.6 eV and 2 eV, respectively, using the Kubelka-Munk transformation of the UV-visible spectra. The micro-Raman spectra of the SnS-A and SnS-B microrods exhibited an Ag mode of SnS at 228.4 and 223 cm-1, respectively. The second peaks at 306.7, and 309 cm-1are associated with the secondary phases of the SnS2phase, whereas the third broad peaks at 616.5, and 613 cm-1revealed that there was a deformation mode of sulfate in the SnS-A and SnS-B samples.