Synthesis and Characterization of Pd(II) And Pt(II) Complexes with Bis [Hg (2-Apt)] Compound.

Abstract

The reaction of one mole of Hg(II) acetate with two mole of 2-amino thiophenol gave one mole of [Hg(2-apt)] compound. While the reaction of one mole of [Hg(2-apt)] with two moles of MCL2 salt. Produced new complexes in general formula [M2{Hg(2-apt)Cl4] where M=Pt(II) or Pd(II).All the prepared complexes were identified using FT-IR, 1H-NMR,13CNMR, elemental analyses (CHNS) and molar conductivity. The results exhibited that metal bounded to the ligand via S and N in squar planer geometries. (English) [ABSTRACT FROM AUTHOR]