Abstract
An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that the process represents a method for the stereoselective directed dihydroxylation of alkenes. © 2014 American Chemical Society.
Cite
CITATION STYLE
APA
Blaisdell, T. P., Caya, T. C., Zhang, L., Sanz-Marco, A., & Morken, J. P. (2014). Hydroxyl-directed stereoselective diboration of alkenes. Journal of the American Chemical Society, 136(26), 9264–9267. https://doi.org/10.1021/ja504228p
Register to see more suggestions
Mendeley helps you to discover research relevant for your work.
Already have an account? Sign in
Sign up for free