Addition of azomethine ylides to carbon-encapsulated iron nanoparticles

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Abstract

The Prato reaction was applied for the covalent introduction of a variety of organic moieties onto carbon-encapsulated iron nanoparticles. The developed method is versatile and employs a broad range of commercially available reactants, including both aromatic and aliphatic aldehydes. The reported functionalization route provides high functionalization yields (ca. 12-21 wt%).

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Kasprzak, A., Nowicka, A. M., Sek, J. P., Fronczak, M., Bystrzejewski, M., Koszytkowska-Stawinska, M., & Poplawska, M. (2018). Addition of azomethine ylides to carbon-encapsulated iron nanoparticles. Dalton Transactions, 47(1), 30–34. https://doi.org/10.1039/c7dt03689b

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