A Novel SERS Substrate Platform: Spatially Stacking Plasmonic Hotspots Films

Abstract

Surface-enhanced Raman scattering (SERS) technique has presented great potential in medical diagnosis, environment monitoring, and food detection due to its high sensitivity, rapid response, and fingerprint effect. Many efforts have been concentrated on all kinds of strategies to produce efficient SERS platforms. Here, we report a simple and controllable method to produce large-area efficient SERS platforms with spatially stacked plasmonic hotspots. The SERS platforms consist of double-layer metal porous films and are easily fabricated by magnetron sputtering and annealing, assisted by the evaporation of hydrofluoric acid. The stacked dual-layer metal porous films show prominent Raman enhancement and ultrasensitive SERS sensing capability for different target molecules. The detection limit is demonstrated down to 10−13 M by detecting rhodamine 6G molecules. These superior Raman properties can be mainly ascribed to the highly dense spatially stacked plasmonic hotspots formed in the dual-layer metal porous films. The simple, controllable, and scalable fabrication strategy and superior Raman performance make these platforms promising candidates for the development of inexpensive, efficient, and mass-produced SERS substrates.