Enhanced reactivity of a biomimetic iron(II) α-keto acid complex through immobilization on functionalized gold nanoparticles

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Abstract

Immobilized biomimetic iron complex: An iron(II) benzoylformate complex of a thiol-appended N4 ligand immobilized on gold nanoparticles activates dioxygen to carry out oxidative decarboxylation of benzoylformic acid to benzoic acid catalytically. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Sheet, D., Halder, P., & Paine, T. K. (2013). Enhanced reactivity of a biomimetic iron(II) α-keto acid complex through immobilization on functionalized gold nanoparticles. Angewandte Chemie - International Edition, 52(50), 13314–13318. https://doi.org/10.1002/anie.201305994

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