A transition metal-gallium cluster formed: Via insertion of "gaI"

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Abstract

The reaction between a two-coordinate Co(ii) diaryl complex and "GaI"affords 2,6-Pmp2C6H3CoGa3I5, in a new geometry for a heavier group 13-transition metal cluster. Experimental and computational investigations show that this compound is best described as a nido metalla-group 13 cluster. This journal is

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Blundell, T. J., Taylor, L. J., Valentine, A. J., Lewis, W., Blake, A. J., McMaster, J., & Kays, D. L. (2020). A transition metal-gallium cluster formed: Via insertion of “gaI.” Chemical Communications, 56(58), 8139–8142. https://doi.org/10.1039/d0cc03559a

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