Evolution of Microstructure, Hardness, and Wear Behavior of Medium-Entropy CuNiSiCrCoTiNbx Alloy

Abstract

Medium-entropy alloys (MEAs) allow the formation of different phases, generally in a solid-solution state, and compounds that favor obtaining alloys with properties superior to those of conventional alloys. In this study, medium-entropy CuNiSiCrCoTiNbx alloys were fabricated via melting in a vacuum induction furnace. The influence of the Nb addition (X = 0, 0.5 and 1 wt%) alloying elements on the microstructure, hardness, and wear resistance of the CuNiSiCrCoTiNb0 (M1), CuNiSiCrCoTiNb0.5 (M2), and CuNiCoCrSiTiNb1 (M3) alloys were explored using X-ray diffraction (XRD), scanning electron microscopy (SEM), and a ball-on-disc tribometer, respectively. In general, the results indicated that the incorporation of Nb alloying element promoted the evolution of the microstructure, increased the hardness, and improvement of the wear resistance. The XRD and SEM findings demonstrate that higher Nb addition and aging heat treatment (AT) modification mainly favored the formation of dendritic regions and the precipitation of the Co2Nb, Cr3Si, and Ni2Si phases, which promoted the refinement and strengthening of the microstructure. Significant increases in hardness were recorded: 11.95% increased, promoted by the addition of Nb before (E1) and after (E2, E3, and E4) the heat treatments. The maximum hardness values recorded were 92 ± 0.11 (AC) and 103 ± 0.5 HRB (AT-60 min) for the M3 alloy. The increase in hardness caused by Nb addition and aging heat treatments contributed to the dry sliding wear resistance response, decreasing material loss by 20%. This was related to the high concentration of precipitated phases rich in CoNb, CrSi, and NiSi with high hardness. Finally, the M3 alloy aged for 60 min exhibited the best specific wear rate behavior, with a material loss of 1.29 (Formula presented.). The commercial Cu-Be C17510 alloy experienced a maximum hardness of 83.47 Hardness Rockwell B, HRB, and a high wear rate of 3.34 mm3.