Research Update: Magnetic phase diagram of EuTi1-x B xO3 (B = Zr, Nb)

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Abstract

We report the magnetic phase diagram of EuTi1-xBxO3 (B = Zr, Nb), determined from magnetization and heat capacity measurements. Upon Zr-doping, the antiferromagnetic ordering temperature TN of EuTi1-xZrxO3 gradually decreases from 5.6 K (x = 0) to 4.1 K (x = 1). Whereas a similar decrease in TN is observed for small amounts of Nb doping (x ≤ 0.05), ferromagnetism is induced in EuTi1-xNbxO3 with x > 0.05. The ferromagnetic interaction between localized Eu 4f spins mediated by itinerant electrons introduced by Nb doping results in the ferromagnetism in EuTi1-xNbxO3.

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Li, L., Zhou, H., Yan, J., Mandrus, D., & Keppens, V. (2014). Research Update: Magnetic phase diagram of EuTi1-x B xO3 (B = Zr, Nb). APL Materials, 2(11). https://doi.org/10.1063/1.4902137

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