Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60·−

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Abstract

The ionic conductivity of [Li+@C60](PF6−) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6−. Electrochemical reduction of [Li+@C60](PF6−) without any supporting electrolyte gave the monovalent radical anion Li+@C60·−, as confirmed by the characteristic ESR signal and NIR absorption band. © 2013 The Royal Society of Chemistry.

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Ueno, H., Kokubo, K., Nakamura, Y., Ohkubo, K., Ikuma, N., Moriyama, H., … Oshimaa, T. (2013). Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60·−. Chemical Communications, 49(67), 7376–7378. https://doi.org/10.1039/c3cc43901a

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