Selective trimerization of α-olefins with triazacyclohexane complexes of chromium as catalysts

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Abstract

Olefin trimers can be prepared selectively from α-olefins with n-alkyl-substituted triazacyclohexane - CrCI3 complexes as catalysts in the presence of methyaluminoxane (MAO).

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Köhn, R. D., Haufe, M., Kociok-Köhn, G., Grimm, S., Wasserscheid, P., & Keim, W. (2000). Selective trimerization of α-olefins with triazacyclohexane complexes of chromium as catalysts. Angewandte Chemie - International Edition, 39(23), 4337–4339. https://doi.org/10.1002/1521-3773(20001201)39:23<4337::AID-ANIE4337>3.0.CO;2-4

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