Abstract
The synthesis of optically enriched compounds is a continuing challenge in organic synthesis. While the Suzuki–Miyaura cross-coupling has been used extensively in the construction of sp2–sp2 bonds, only recently has it come to prominence as a useful means to construct stereogenic centres. This chapter describes the latest achievements in the development of stereoselective Suzuki–Miyaura cross-coupling reactions, including advances made both in atroposelective couplings as well as stereoselective C(sp3) couplings. Focus is also given to the mechanistic details of these cross-coupling processes.
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Sun, H. Y., & Hall, D. G. (2015). Synthesis and Application of Organoboron Compounds. (E. Fernández & A. Whiting, Eds.), Topics in Organometallic Chemistry (Vol. 49, pp. 221–242). Springer International Publishing. Retrieved from http://link.springer.com/10.1007/978-3-319-13054-5
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