Towards a Pseudocapacitive Battery: Benchmarking the Capabilities of Quantized Capacitance for Energy Storage

Abstract

Despite being capable of very fast charging, the pseudocapacitive properties of electrochemical capacitors still require significant research to attain energy densities comparable to that of batteries. Herein we discuss and theoretically benchmark the physics of quantized capacitance as a Faradaic charge storage mechanism, providing near "ideal"pseudocapacitive properties in the context of batterylike energy storage. Through careful electrolyte and reactant engineering, our physical analysis suggests that this less explored "pseudocapacitive battery"mechanism could provide power densities of approximately 104 W/L combined with volumetric energy densities in the range of 100 Wh/L (or potentially greater). These benchmarks are arrived at though a comprehensive analysis of two-dimensional (2D) graphitic nanoparticles considering the impact of solvation, electron-electron interactions, and electron transfer processes. In general, our findings indicate that 2D nanomaterials exhibiting quantized capacitance provide a promising and underexplored physical axis within electrochemical capacitors towards realizing very fast charging at energy densities comparable to that of batteries.