Research on the treatment and comprehensive utilization of phenylhydrazine hydrochloride effluent

Abstract

In the production process of 1 ton of phenylhydrazine hydrochloride (PHH); ~10 tons of liquid waste are formed, which includes multiple contaminants but also recyclable resources. In order to realize the recyclingof residual PHH in liquid waste; a liquid ammonia neutralization method is utilized, and extraction-reextraction technology is adopted. As a result, the recovery rate of PHH reachedup to 90.0%. Meanwhile, 3.8 tons of ammonium salts can be obtained after the iquid ammonia neutralization reaction which can be reused as raw materials for compound fertilizer. During the treatment process, there is no discharge of the three wastes, which meets the requirements of harmless treatment. Finally, these results provide important reference values for PHH production enterprises to solve the problems of waste pollution and to achieve recycling of resources.