Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior

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Abstract

Two new coordination polymers based on Zn(II) and 2,5-diiodoterephthalate—{[Zn(2,5-I-bdc)bpe}] (1) and {[Zn(2,5-I-bdc)bpen}] (2)—were synthesized and characterized. Polymers 1 and 2 feature halogen bonding between the I atoms of MOF and DMF guest molecules, which plays a crucial role in structure stabilization. Selectivity of sorption towards different organic substrates was examined.

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Zaguzin, A. S., Sukhikh, T., Sokolov, M. N., Fedin, V. P., & Adonin, S. A. (2023). Zn(II) Three-Dimensional Metal-Organic Frameworks Based on 2,5-Diiodoterephthalate and N,N Linkers: Structures and Features of Sorption Behavior. Inorganics, 11(5). https://doi.org/10.3390/inorganics11050192

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