Alternative Methods for Biodiesel Cetane Number Valuation: A Technical Note

Abstract

Biodiesel is an environmentally beneficial and clean energy source that may replace fossil fuels, which are detrimental to the environment and cannot be replenished. Therefore, the physicochemical parameters of biodiesel must be determined in order to verify its quality. The cetane number is a crucial dimensionless fuel property that gauges the fuel ignition quality in power diesel engines. A higher cetane number results in a shorter ignition delay time, and vice versa. Biodiesel’s cetane number may fluctuate due to a variety of fatty acid compositions, including variations in carbon chain length and the degree of unsaturation. The cetane number generally increases with increasing saturation and chain length, while it decreases as chain length is reduced and degrees of unsaturation and branching increase. This is the main reason for why alkanes possess a higher cetane number than alkenes and aromatics. The standard protocols for evaluating the cetane number of biodiesel are ASTM D613 and ISO 5165 test techniques using a monocylindrical cetane engine. However, adhering to these conventional procedures is quite challenging and time-consuming, and the cetane number test result may also be affected by the presence of certain gases and fumes. As a result, many researchers are bothered with cetane number valuation, and occasionally they skip it due to a lack of other options. Consequently, the aim of this paper is to present a set of more straightforward and relevant alternative techniques that can be applied to predict the cetane number of biodiesel when engine-based measurement is not practical. The three techniques with their designed pictographic outlooks conferred in this article include color indicator titration, aniline point, and fatty acid composition-based methods. The reported values of these procedures meet the minimum cut point of the biodiesel cetane number required by ASTM D6751 (≥47) and exhibit minimal variation from the typical standard methods. Nevertheless, the above-mentioned techniques are not applicable to other alternative biofuels except biodiesel products because they have a direct implication on the characteristics of the fatty acid profiles of different oil precursors, such as carbon chain length, degree of saturation or unsaturation, and aromaticity, which make up monoalkyl esters.