Nanocrystalline cermet coatings for erosion-corrosion protection

Abstract

The processing techniques, microstructural characteristics, and erosion corrosion behaviour of Cr3C2-NiCr and tungsten carbide (WC)-based cermet coatings are reviewed in this work. Conventional and nanocrystalline Cr3C2-NiCr and WC-based cermet coatings are generally synthesized using thermal spray technique. The wear, erosion, and corrosion protection ability of conventional and nanocermet coatings are compared based on available literature. In Cr3C2-NiCr coatings, the corrosion resistance is offered by NiCr metal matrix while the wear resistance is provided by the carbide ceramic phase, making it suitable for erosion-corrosion protection. The nanocrystalline cermet coatings exhibits better erosion-corrosion resistance as compared to the conventional coatings. The nanocrystalline coatings reduces the erosion-corrosion rate significantly compared to conventional coatings. It is attributed to the presence of the protective NiCr metallic binder that allows easier and faster re-passivation when the coating is subjected to wear and the fine-grain structure with homogeneous distribution of the skeleton network of hard carbide phases. In addition, corrosion-accelerated erosion dominates the reaction mechanism of erosion-corrosion and, therefore, higher hardness, strength, and better wear resistance of nanocermet coating along with its faster repassivation kinetics accounts for improved corrosion resistance as compared to conventional coatings.