(Acetyl-acetonato)dibromido[2,2-diphenyl-hydrazin-1-ido(1-)][2, 2-diphenyl-hydrazin-1-ido(2-)]molybdenum(VI)

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Abstract

In the title compound, [MoBr2(C12H11N 2)(C12H10N2)(C5H 7O2)], the MoVI atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from the diphenyl-hydrazide(1-) and diphenyl-hydrazide(2-) ligands, two O atoms from a bidentate acetyl-acetonate ligand and two Br- ions. The mol-ecules form an inversion dimer via a pair of weak C - H⋯O hydrogen bonds and a π-π stacking inter-action with a centroid-centroid distance of 3.7401 (12) Å. Weak intra-molecular C - H⋯Br inter-actions and an intra-molecular π-π stacking inter-action with a centroid-centroid distance of 3.8118 (15) Å are also observed.

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Bustos, C., Alvarez-Thon, L., Ibãez, A., & Sánchez, C. (2011). (Acetyl-acetonato)dibromido[2,2-diphenyl-hydrazin-1-ido(1-)][2, 2-diphenyl-hydrazin-1-ido(2-)]molybdenum(VI). Acta Crystallographica Section E: Structure Reports Online, 67(6). https://doi.org/10.1107/S1600536811015881

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