Scattering matrices of mineral dust aerosols: A refinement of the refractive index impact

Abstract

Mineral dust, as one of the most important aerosols, plays a crucial role in the atmosphere by directly interacting with radiation, while there are significant uncertainties in determining dust optical properties to quantify radiative effects and to retrieve their properties. Laboratory and in situ measurements of the refractive indices (RIs) of dust differ, and different RIs have been applied in numerical studies used for model developments, aerosol retrievals, and radiative forcing simulations. This study reveals the importance of the dust RI for the development of a model of dust optical properties. The Koch-fractal polyhedron is used as the modeled geometry, and the pseudospectral time domain method and improved geometric-optics method are combined for optical property simulations over the complete size range. We find that the scattering matrix elements of different kinds of dust particles are reasonably reproduced by choosing appropriate RIs, even when using a fixed particle geometry. The uncertainty of the RI would greatly affect the determination of the geometric model, as a change in the RI, even in the widely accepted RI range, strongly affects the shape parameters used to reproduce the measured dust scattering matrix elements. A further comparison shows that the RI influences the scattering matrix elements in a different way than geometric factors, and, more specifically, the P11, P12, and P22 elements seem more sensitive to the RI of dust. In summary, more efforts should be devoted to account for the uncertainties on the dust RI in modeling its optical properties, and the development of corresponding optical models can potentially be simplified by considering only variations over different RIs. Considerably more research, especially from direct measurements, should be carried out to better constrain the uncertainties related to the dust aerosol RIs.